dc.contributor.author | SENGE, MATHIAS | en |
dc.date.accessioned | 2015-08-26T11:08:33Z | |
dc.date.available | 2015-08-26T11:08:33Z | |
dc.date.created | 2015 | en |
dc.date.issued | 2015 | en |
dc.date.submitted | 2015 | en |
dc.identifier.citation | Plunkett S, Flanagan K.J, Twamley B, Senge M.O, Highly Strained Tertiary sp3 Scaffolds: Synthesis of Functionalized Cubanes and Exploration of Their Reactivity under Pd(II) Catalysis, Organometallics, 34, 7, 2015, 1408 - 1414 | en |
dc.identifier.other | Y | en |
dc.identifier.uri | http://hdl.handle.net/2262/74515 | |
dc.description.abstract | A series of chemically distinct, highly strained, activated cubane scaffolds was synthesized through optimization of
the metal-halogen exchange reactions of iodinated cubane derivatives. This included the first reported successful attachment of both
boron and phosphorous; key elements in potential transition metal-catalyzed cross coupling reactions; on the cubane scaffold. Additionally,
Zn, Sn, Si, S and various C-based systems were also attached in a high-yielding, one-pot reaction from readily available
precursors. A comprehensive program investigating the reactivity of these tertiary cubane nucleophiles towards Suzuki-Miyaura,
Negishi and Stille cross-coupling methods, never previously reported with the cubane scaffold; is also described, but proved unsuccessful. | en |
dc.format.extent | 1408 | en |
dc.format.extent | 1414 | en |
dc.relation.ispartofseries | Organometallics | en |
dc.relation.ispartofseries | 34 | en |
dc.relation.ispartofseries | 7 | en |
dc.rights | Y | en |
dc.subject | metal-halogen exchange | en |
dc.subject.lcsh | metal-halogen exchange | en |
dc.title | Highly Strained Tertiary sp3 Scaffolds: Synthesis of Functionalized Cubanes and Exploration of Their Reactivity under Pd(II) Catalysis | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | en |
dc.identifier.rssinternalid | 105604 | en |
dc.identifier.doi | http://dx.doi.org/10.1021/acs.organomet.5b00151 | en |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.rssuri | http://www.scopus.com/inward/record.url?eid=2-s2.0-84927638992&partnerID=40&md5=d66999e6346d54291e032a4840ad1ca7 | en |