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Universal Scaling Relations for the Rational Design of Molecular Water Oxidation Catalysts with Near-Zero Overpotential
(2019)A major roadblock in realizing large-scale production of hydrogen via electrochemical water splitting is the cost and inefficiency of current catalysts for the oxygen evolution reaction (OER). Computational research has ... -
Investigations into Metal-Binding Groups to Probe the DNA Repair Nuclease SNM1A
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2021)SNM1A is a nuclease that is implicated in DNA interstrand crosslink repair and as such is of importance to regular cellular function. However, little is known about its roles, regulation, interaction partners or posttranslational ... -
Synthesis and Spectral Properties of gem-Dimethyl Chlorin Photosensitizers
(2020)Chlorins that bear a gem‐dimethyl group, which facilitates their resistance to oxidation, are of interest for applications in photomedicine. Herein, we present the synthesis and the photophysical properties of two ... -
Dual-binding conjugates of diaromatic guanidines and porphyrins for recognition of G-quadruplexes
(2020)The first conceptualised class of dual-binding guanine quadruplex binders has been designed, synthesised and biophysically studied. These compounds combine diaromatic guanidinium systems and neutral tetra-phenylporphyrins ... -
Graphene Oxide Functionalized with Cationic Porphyrins as Materials for the Photodegradation of Rhodamine B
(2020)Two noncovalent nanohybrids between cationic porphyrin (free-base TMPyP and zinc(II) ZnTMPyP) bearing cationic (N-methylpyridyl) groups and graphene oxide (GO) were constructed with the aim of generating a photocatalyst ...
