stoichiometry Tb(III) Eu(III) luminescent complexes tryptophan based ligands
Royal Society of Chemistry
Lincheneau, C., Leonard, J.P., McCabe, T., Gunnlaugsson, T., Lanthanide directed self-assembly formations of Tb(iii) and Eu(iii) luminescent complexes from tryptophan based pyridyl amide ligands, Chemical Communications, 47, 25, 2011, 7119-7121
Chemical Communications;47, 25
The formation of self-assembly complexes between the ligands 1 (SS) and 2 (RR) and terbium or europium was undertaken and shown (using various spectroscopic titrations) to give rise to the exclusive formation of 2 : 1 (L : Ln) stoichiometry and not the anticipated 3 : 1 stoichiometry.
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