Synthesis of porphyryl boronates with (un)saturated side-chains
Citation:N. N. Sergeeva, V. Pablo Lopez, M. O. Senge, Synthesis of porphyryl boronates with (un)saturated side chains, Journal of Organometallic Chemistry, 693, 15, 2008, 2637 - 2640
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Porphyrins with (un)saturated side?chains containing boron residues were developed as synthons for porphyrin functionalization. Porphyrins with mono and bis-substituted unsaturated boronyl residues were prepared in good yields (52?66 %) using a cross?metathesis approach in the presence of Grubbs I-generation catalysts. In all cases complete E?stereoselectivity (100 %) was observed. Furthermore, formal cross?metathesis products with ?,??unsaturated chains smoothly underwent addition with bis(pinacolato)diboron [(Me4C2O2)B?B(O2C2Me4)] to yield the corresponding saturated boron compounds in 60?70 % yields.
Science Foundation Ireland (SFI)
Type of material:Journal Article
Series/Report no:Journal of Organometallic Chemistry
Availability:Full text available