Browsing Chemistry (Scholarly Publications) by Title
Now showing items 826-845 of 876
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Transparent ultrathin conducting carbon films
(2010)Ultrathin conductive carbon layers (UCCLs) were created by spin coating resists and subsequently converting them to conductive films by pyrolysis. Homogeneous layers as thin as 3 nm with nearly atomically smooth surfaces ... -
Transparent, Flexible Silicon Nanostructured Wire Networks with Seamless Junctions for High-Performance Photodetector Applications
(2018)Optically transparent photodetectors are crucial in next-generation optoelectronic applications including smart windows and transparent image sensors. Designing photodetectors with high transparency, photoresponsivity, and ... -
Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance
(2017)2D transition‐metal carbides and nitrides, known as MXenes, have displayed promising properties in numerous applications, such as energy storage, electromagnetic interference shielding, and catalysis. Titanium carbide MXene ... -
Transport and kinetics at carbon nanotube- redox enzyme composite modified electrode biosensors. Part 2. Redox enzyme dispersed in nanotube mesh of finite thickness.
(Electrochemical Science Group, 2009)A mathematical model describing the transport and kinetics of substrate and redox mediator in surface deposited films of finite thickness is described. These bio-catalytically active chemically modified electrodes comprise ... -
Transport and kinetics at carbon nanotube-redox enzyme composite modified electrode biosensors
(Electrochemical Science Group, 2009)A mathematical model describing transport and kinetics of substrate and redox mediator within chemically modified electrodes comprising of redox enzymes immobilized in dispersed carbon nanotube meshes dispersed on support ... -
Trends and targets in antiviral phototherapy
(2019)Photodynamic therapy (PDT) is a well‐established treatment option in the treatment of certain cancerous and pre‐cancerous lesions. Though best‐known for its application in tumor therapy, historically the photodynamic ... -
Tri- and tetra-substituted cyclen based lanthanide(III) ion complexes as ribonuclease mimics: A study into the effect of log K<inf>a</inf>, hydration and hydrophobicity on phosphodiester hydrolysis of the RNA-model 2-hydroxypropyl-4-nitrophenyl phosphate (HPNP)
(2015)A series of tetra-substituted ‘pseudo’ dipeptide ligands of cyclen (1,4,7,10,-tetraazacyclododecane) and a tri-substituted 3′-pyridine ligand of cyclen, and the corresponding lanthanide(III) complexes were synthesised and ... -
Tricarbonyl (h6-pyridine)chromium (0)
(1994)The molecular structure of tricarbonyl(rl6-pyridine) - chromium(0), [Cr(CO)3(C5H5N)], is presented here. The Cr atom is bound to the pyridine ring via the 7r-electron system and is situated dir ... -
Tunable bromomagnesium thiolate Tishchenko reaction catalysts: efficient intermolecular aldehyde-trifluoromethylketone coupling
(2010)A new thiolate-catalyzed Tishchenko reaction inspired by biochemical processes features exceptionally good control over the catalyst's steric/electronic properties. The isolation of reaction intermediates provided valuable ... -
Tuning photoactive metal–organic frameworks for luminescence and photocatalytic applications
(2021)Metal-organic frameworks (MOFs) are a class of porous materials, constructed from organic and inorganic components. MOFs have been explored for a diverse range of applications due to their tunable structures, porosities, ... -
Tuning the Catalytic Water Oxidation Activity through Structural Modifications of High-Nuclearity Mn-oxo Clusters [Mn18M] (M = Sr2+, Mn2+)
(2021)The water oxidation half-reaction is considered the bottleneck in the development of technological advances to replace fossil fuels with sustainable and economically affordable energy sources. In natural photosynthesis, ... -
Tuning the Electro-Optical Properties of Nanowire Networks
(2021)Conductive and transparent metallic nanowire networks are regarded as promising alternatives to Indium–Tin–Oxides (ITOs) in emerging flexible next-generation technologies due to their prominent optoelectronic properties ... -
Tuning the Photo-electrochemical Performance of RuII-Sensitized Two-Dimensional MoS2
(2020)Covalently tethering photosensitizers to catalytically active 1T-MoS2 surfaces holds great promise for the solar-driven hydrogen evolution reaction (HER). Herein, we report the preparation of two new RuII-complex-functionalized ... -
"Turn-on" fluorescence sensing of volatile organic compounds using a 4-amino-1,8-naphthalimide Tröger's base functionalised triazine organic polymer
(2019)The 4-amino-1,8-naphthalimide Tröger's base functionalized triazine covalent organic polymer TB-TZ-COP was synthesised and employed as a “turn-on” fluorescent and a colorimetric sensor for the discriminative sensing of ... -
Two-dimensional material inks.
(2002)The development of new and more accurate fabrication technologies has, in the past few years, boosted interest in advanced device manufacturing. 2D materials, thanks to their diverse properties and dispersibility in liquid ... -
Two-dimensional materials as catalysts for energy conversion
(2016)Although large efforts have been dedicated to studying two-dimensional materials for catalysis, a rationalization of the associated trends in their intrinsic activity has so far been elusive. In the present work we employ ... -
Two-Dimensional MoS2 Catalyzed Oxidation of Organic Thiols
(2018)Thiol-chemistry directed techniques have been extensively employed to modify the properties of two-dimensional MoS2 nanosheets, aiming to heal or functionalize sulfur vacancies. However, the exact nature of the organic ... -
Two-Photon Absorption in Monolayer MXenes
(2020)Two‐photon absorption (2PA) is a nonlinear optical (NLO) effect that typically occurs in a conventional semiconductor whose bandgap is larger than the energy of one excited photon but smaller than the energy of two photons. ... -
Two-Photon Polymerization of Sugar Responsive 4D Microstructures
(2023)Stimuli-responsive hydrogels have attracted much attention owing to the versatility of their programmed response in offering intelligent solutions for biomimicry applications, such as soft robotics, tissue engineering, and ...