The synthesis, characterisation and photophysical properties of novel tri-substituted-8-azafluoranthene compounds and their Cu(1) complexes
Citation:
Amy Theresa Nordon, 'The synthesis, characterisation and photophysical properties of novel tri-substituted-8-azafluoranthene compounds and their Cu(1) complexes', [thesis], Trinity College (Dublin, Ireland). School of Chemistry, 2012, pp 250Download Item:
Abstract:
Chapter 1: This chapter details the synthesis and charaeterisation of a family of novel
tri-substituted-8-azafluoranthene eompounds that have N^N bidentate ligand
capabilities. The compounds are synthesised via a Diels-Alder cycloaddition and two
methods of synthesis are employed; a conventional method using a sand bath to heat
the reaction and a microwave assisted method. The methods are compared for
efficiency. The resulting six compounds; 7,10-diphenyl-9-(2-pyridyl)-8-
azafluoranthene (6), 7,10-diphenyl-9-(6-methyl-2-pyridyl)-8-azafluoranthene (7), 7,10-
diphenyl-9-(6-cyano-2-pyridyl)-8-azafluoranthene (8), 7,10-di(4-tert-butylphenyl)-9-
(2-pyridyl)-8-azafluoranthene (9), 7,10-di[(4-trifluoromethyl)phenyl]-9-(2-pyridyl)-8-
azafluoranthene (10) and 7,10-di(4-tert-butylphenyl)-9-(6-cyano-2-pyridyl)-8-
azafluoranthene (13) are fully characterised by NMR and mass spectrometry.
Author: Nordon, Amy Theresa
Advisor:
Draper, SylviaQualification name:
Doctor of Philosophy (Ph.D.)Publisher:
Trinity College (Dublin, Ireland). School of ChemistryNote:
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Chemistry, Ph.D., Ph.D. Trinity College Dublin.Metadata
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