{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate
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Marzec B, Mariyatra MB, McCabe T, Schmitt W, {4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate, Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1073-m1074Download Item:
{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-?N)hydrazinyl-?N]pyrimidine-?N}dichloridocopper(II) methanol disolvate monohydrate.pdf (Published (publisher's copy) - Peer Reviewed) 787.4Kb
Abstract:
The title compound, [CuCl2(C18H18N8)]?2CH3OH?H2O, contains a pentacoordinated Cu(II) atom bonded to the tridentate 4,6-bis[(E)-1-methyl-2-(pyridin-2-ylmethylidene)hydrazinyl]pyrimidine ligand and two Cl atoms. The geometry around the CuII atom is distorted square-pyramidal. The molecules pack in the crystal structure via O-HCl, O-HN, C-HCl and C-HO hydrogen bonds, C-H and - interactions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine interactions are 3.750 (3) and 3.850 (3) ?, respectively], forming sheet-like assemblies.
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Grant Number
Science Foundation Ireland (SFI)
08/IN.1/I2047
Science Foundation Ireland (SFI)
06/RFP/CHE174
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http://people.tcd.ie/tmccabehttp://people.tcd.ie/schmittw
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Acta crystallographica. Section E, Structure reports online67
Pt 8
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Chemistry, CrystallographySubject (TCD):
Nanoscience & MaterialsDOI:
http://dx.doi.org/10.1107/S1600536811025414ISSN:
1600-5368Licences: