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Anion templated self-assembly - From anion complexes to the formation of supramolecular 2D networks
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2019)This thesis, entitled “Anion Templated Self-Assembly – From Anion Complexes to the Formation of Supramolecular 2D Networks” covers the anion complexation and ATSA abilities of different sets of ligands. The work will be ... -
Mimicking ribonucleotide reductases: Biomimetic manganese complexes and their reaction with superoxide
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2019)An important discovery in class Ib ribonucleotide reductase’s chemistry has been the identification of a MnII2 active site, that required a superoxide anion (O2•–), rather than dioxygen (O2), to access a high-valent MnII2 ... -
Supramolecular soft materials and structural studies of a series of BTA and pyridine-dicarboxamide derivatives with various d-metal ions
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2019)As will be discussed in the introduction, the control and tuning of the self-assembly of supramolecular soft materials is an area of great current interest and importance. A particularly interesting motif for investigating ... -
Transmission electron microscopy and spectroscopy of carbon-based nanomaterials
(Trinity College (Dublin, Ireland). School of Chemistry, 2016)Carbon-based nanomaterials, such as graphene, Carbon Nanotubes and fullerenes, have attracted a great deal of interest from the materials research community; especially in electronic and sensing applications. Despite all ... -
Formation of an ordered porous polymer microstructure by water droplet templating
(Trinity College (Dublin, Ireland). School of Chemistry, 2010)This thesis examines the complex system of competing mechanisms involved when evaporation of a polymer solution induces sufficient cooling to drive condensation of water droplets onto the solution surface, where they pack, ...
