Browsing Chemistry (Scholarly Publications) by Title
Now showing items 21-40 of 875
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Advanced materials of printed wearables for physiological parameter monitoring
(2020)The consumer demand for flexible wearables has increased rapidly with the advent of recent commercial health monitoring systems. The progress in wearable electronics for monitoring physiological parameters in the healthcare ... -
Aerobic oxidation of NHC-catalysed aldehyde esterifications with alcohols: Benzoin, not the Breslow intermediate, undergoes oxidation
(2013)Benzoin (and neither the Breslow intermediate nor the NHC–aldehyde tetrahedral adduct) has been unambiguously identified as the oxidised species in aerobic NHC-catalyse d aldehyde esterifications. -
Alcohol Pre-treatment to Eliminate the Interference of Micro Additive Particles in the Identification of Microplastics Using Raman Spectroscopy
(2022)Raman spectroscopy is an indispensable tool in the analysis of microplastics smaller than 20 μm. However, due to its limitation, Raman spectroscopy may be incapable of effectively distinguishing microplastics from micro ... -
Altering the nature of coupling by changing the oxidation state in a {Mn6} cage
(2020)Polynuclear transition metal complexes have continuously attracted interest owing to their peculiar electronic and magnetic properties which are influenced by the symmetry and connectivity of the metal centres. Understanding ... -
Amino-Functionalized Mesoporous Silica Nanoparticle-Encapsulated Octahedral Organoruthenium Complex as an Efficient Platform for Combatting Cancer
(American Chemical Society (ACS), 2020)In the process of synthesis of a new drug, as important as the drug itself is the formulation used, because the same compound can present a very different efficacy depending on how it is administered. In this work, we ... -
Anion-directed supramolecular chemistry modulating the magnetic properties of nanoscopic Mn coordination clusters: From polynuclear high-spin complexes to SMMs
(2016)We report a supramolecular approach to mixed-valent Mn coordination clusters that demonstrates how halide ions can be applied to in fl uence the assembly of distinct tetranuclear building units to produce a number of ... -
Anthracenylporphyrins
(2010)We report the synthesis and characterization of meso-anthracenylporphyrins with zinc and nickel metal centers. A variety of novel aryl and alky meso substituted anthracenylporphyrins were synthesized via step-wise Suzuki ... -
Assembly, disassembly and reassembly: a “top-down” synthetic strategy towards hybrid, mixed-metal {Mo10Co6} POM clusters
(2019)Polyoxometalates (POMs) are commonly prepared using a “bottom-up” synthetic procedure. The alternative “top-down” approach of disassembling a pre-formed POM unit to generate new synthetic intermediates is promising, but ... -
Assembly, disassembly and reassembly: a “top-down” synthetic strategy towards hybrid, mixed-metal {Mo10Co6} POM clusters
(2019)Polyoxometalates (POMs) are commonly prepared using a “bottom-up” synthetic procedure. The alternative “top-down” approach of disassembling a pre-formed POM unit to generate new synthetic intermediates is promising, but ... -
Associative Enhancement of Time Correlated Response to Heterogeneous Stimuli in a Neuromorphic Nanowire Device
(2016)In spite of the strong interest in brain‐like or neuromorphic computation, relatively few devices have emerged whose neuromorphic behavior is embedded in the hardware itself and not reliant on external programming of ... -
Asymmetric acyl-transfer promoted by readily assembled chiral 4-N,N-dialkylaminopyridine derivatives
(Royal Society of Chemistry, 2006)The development of a new class of chiral 4-N,N-dialkylaminopyridine acyl-transfer catalysts capable of exploiting both van der Waals (?) and H-bonding interactions to allow remote chiral information to stereochemically ... -
Asymmetric organocatalytic reductions mediated by dihydropyridines
(Royal Society of Chemistry, 2007)Catalytic asymmetric reduction reactions have long been the preserve of the transition metal catalyst. Inspired by the myriad efficient enzyme-catalysed reduction reactions routine in biological systems, chemists have ... -
Asymmetric spin crossover behaviour and evidence of light-induced excited spin state trapping in a dinuclear iron(II) helicate
(2009)Reported herein are the synthesis, structural and magnetic characterisation of a dinuclear FeII triple helicate that displays an unprecedented reversible asymmetric high spin to low spin crossover characterised by a thermal ... -
Asymmetrical Diaromatic Guanidinium/2-Aminoimidazolinium Derivatives: Synthesis and DNA Affinity
(2009)In this paper we report the synthesis of three families of new amidine?based aromatic derivatives as potential DNA minor groove binding agents for the treatment of cancer. The preparation of mono?guanidine, mono?2?aminoimidazoline ...