Asymmetric spin crossover behaviour and evidence of light-induced excited spin state trapping in a dinuclear iron(II) helicate
Citation:
Pelleteret D, Clerac R, Mathoniere C, Harte E, Schmitt W, Kruger PE, Asymmetric spin crossover behaviour and evidence of light-induced excited spin state trapping in a dinuclear iron(II) helicate, Chemical Communications, 2, 2, 2009, 221 - 223Download Item:

Abstract:
Reported herein are the synthesis, structural and magnetic characterisation of a dinuclear FeII triple helicate that displays an unprecedented reversible asymmetric high spin to low spin crossover characterised by a thermal hysteresis: indeed the high spin state can be recovered by white light irradiation at 10 K.
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http://people.tcd.ie/schmittwDescription:
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Author: SCHMITT, WOLFGANG
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Chemical Communications;2;
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FeII triple helicateLicences: