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dc.contributor.authorFLEISCHER, KARSTENen
dc.contributor.authorARCA, ELISABETTAen
dc.contributor.authorSHVETS, IGORen
dc.date.accessioned2013-11-18T17:01:23Z
dc.date.available2013-11-18T17:01:23Z
dc.date.issued2013en
dc.date.submitted2013en
dc.identifier.citationElisabetta Arca, Karsten Fleischer, Sergey A. Krasnikov, and Igor Shvets, Effect of Chemical Precursors On the Optical and Electrical Properties of p‐Type Transparent Conducting Cr2O3:(Mg,N), The Journal of Physical Chemistry C, 117, 42, 2013, 21901 - 21907en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/67643
dc.descriptionPUBLISHEDen
dc.description.abstractCr2O3:(Mg,N) has been reported as a p-type transparent conducting oxide. In this contribution the effect of each precursor used for the deposition by spray-pyrolysis, will be explored and their role in determining the optical and electrical properties of Cr2O3 will be outlined. A correlation between the structural, electrical, and optical properties upon introducing nitrogen precursors has been established. In particular it has been shown that the presence of ammonium salts in the deposition environment results in less absorbing films. By combining optical measurements and NEXAFS studies, a mechanism is proposed to explain the change in the optical properties. Moreover, it is shown that the presence of the nitrate moiety in the reaction environment is necessary to improve the electrical conductivity of the deposited films. The reaction of the nitrate moiety with the ammonium moiety has been proposed as the mechanism to explain the boost in conductivity.en
dc.description.sponsorshipSFI 06/IN.1/I91 TIDA Feasibility 11en
dc.format.extent21901en
dc.format.extent21907en
dc.language.isoenen
dc.relation.ispartofseriesThe Journal of Physical Chemistry Cen
dc.relation.ispartofseries117en
dc.relation.ispartofseries42en
dc.rightsYen
dc.subjectdefect chemistryen
dc.subjectp-type TCOen
dc.subjectCr2O3en
dc.subjectnexafsen
dc.subjectspray pyrolysisen
dc.subjecttransparent conducting oxideen
dc.titleEffect of Chemical Precursors On the Optical and Electrical Properties of p‐Type Transparent Conducting Cr2O3:(Mg,N)en
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/fleiscken
dc.identifier.peoplefinderurlhttp://people.tcd.ie/ivchvetsen
dc.identifier.rssinternalid89319en
dc.identifier.doihttp://dx.doi.org/10.1021/jp404230ken
dc.rights.ecaccessrightsOpenAccess
dc.contributor.sponsorGrantNumberSFI 06/IN.1/I91 TIDA Feasibility 11en
dc.subject.TCDThemeNanoscience & Materialsen
dc.subject.TCDThemeSmart & Sustainable Planeten


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