Browsing Chemistry by Author "Baker, Robert"
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An investigation of the interactions of Eu3+ and Am3+ with uranyl minerals: implications for the storage of spent nuclear fuel.
Baker, Robert; Mc Kenna, Cora (2016)The reaction of a number of uranyl minerals of the (oxy)hydroxide, phosphate and carbonate types with Eu( III ), as a surrogate for Am( III ), have been investigated. A photoluminescence study shows that Eu( III ) ... -
Perfluorinated phosphine and hybrid P-O ligands for Pd catalysed C-C bond forming reactions in solution and on Teflon supports
Baker, Robert; Begum, Farzana; Ikram, Muhammad; Twamley, Brendan (2019)The synthesis of two types of phosphine ligands that feature perfluorinated ponytails is reported. A bidentate (RfCH2CH2)2PCH2CH2P(CH2CH2Rf)2 (Rf = CF3(CF2)n; n = 5, 7) and an alkoxyphosphine made by ring opening a fluorous ... -
A structural and spectroscopic study of the first uranyl selenocyanate, [Et4N]3[UO2(NCSe)5]
Baker, Robert; Browne, Michelle (2016)he first example of a uranyl selenocyanate compound is reported. The compound [Et4N]3[UO2(NCSe)5] has been synthesized and fully characterized by vibrational and multinuclear (1H, 13C{1H} and 77Se{1H}) NMR spectroscopy. ...