• Mixed donor, phenanthroline photoactive MOFs with favourable CO 2 selectivity

    Thumbnail Image

    Files

    Macreadie.pdf (1.82 MB)

    Date

    2020

    Authors

    Journal Title

    Journal ISSN

    Volume Title

    Publisher

    Access

    openAccess

    Embargo end date

    Citation

    Setter, C.J. and Price, M.B. and Conte, L. and Schmitt, W. and Batten, S.R. and Richardson, C. and Hill, M.R. and Babarao, R. and MacReadie, L.K., Mixed donor, phenanthroline photoactive MOFs with favourable CO 2 selectivity, Chemical Communications, 2020, 56, 87, 13377-13380

    Abstract

    Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

    Description

    URI

    http://hdl.handle.net/2262/98409

    Collections

    Chemistry (Scholarly Publications)
    RSS Feeds

    Endorsement

    Review

    Supplemented By

    Referenced By

    Keywords

    Author's Homepage: http://people.tcd.ie/schmittw

    Author: Schmitt, Wolfgang

    Type of material: Journal Article