• A cubane-type manganese complex with H2O oxidation capabilities

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    2020

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    Tandon, Swetanshu, Soriano-López, Joaquín, Kathalikkattil, Amal C., Jin, Guanghua, Wix, Paul, Venkatesan, Munuswamy, Lundy, Ross, Morris, Michael A., Watson, Graeme W., Schmitt, Wolfgang, A cubane-type manganese complex with H2O oxidation capabilities, Sustainable Energy & Fuels, 2020, 4, 9, 4464 - 4468

    Abstract

    We report the synthesis and characterisation of [Mn8K2O4(OH)2((CH3)3CCOO)16(CH3CN)2] whose cluster core shares some features with the oxygen evolving complex (OEC), the natural water oxidation catalyst. Importantly, this complex provides a bio-inspired complex that promotes catalytic H2O oxidation at neutral pH value.

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    http://hdl.handle.net/2262/98412

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    Chemistry (Scholarly Publications)
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    Author's Homepage: http://people.tcd.ie/schmittw

    Author: Watson, Graeme

    Author: Schmitt, Wolfgang

    Author: Venkatesan, Munuswamy

    Type of material: Journal Article