Lanthanide directed self-assembly formations of Tb(iii) and Eu(iii) luminescent complexes from tryptophan based pyridyl amide ligands

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Lincheneau, C., Leonard, J.P., McCabe, T., Gunnlaugsson, T., Lanthanide directed self-assembly formations of Tb(iii) and Eu(iii) luminescent complexes from tryptophan based pyridyl amide ligands, Chemical Communications, 47, 25, 2011, 7119-7121

Abstract

The formation of self-assembly complexes between the ligands 1 (SS) and 2 (RR) and terbium or europium was undertaken and shown (using various spectroscopic titrations) to give rise to the exclusive formation of 2 : 1 (L : Ln) stoichiometry and not the anticipated 3 : 1 stoichiometry.

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Sponsor: Science Foundation Ireland (SFI)
Grant Number: SFI, RFP 2008 & 2009

Type of material: Journal Article