Observation of pentacarbonylchromium on flash photolysis of exacarbonylchromium in cyclohexane solution

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J.M. Kelly, H. Hermann and E. Koerner von Gustorf, Observation of pentacarbonylchromium on flash photolysis of exacarbonylchromium in cyclohexane solution, J.C.S. Chem. Comm., 1973, 105-106

Abstract

The first observable transient (lifetime > 50 ns) on flash photolysis of Cr(CO), is Cr(CO),, which is the precursor of two species previously assigned to the D,, and C,, forms of Cr(CO),, and now shown to arise from reaction with impurities.

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Author's Homepage: http://people.tcd.ie/jmkelly
Type of material: Journal Article