• Chemoselective crossed acyloin condensations: catalyst and substrate control

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    2011

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    C. A. Rose, S. Gundala, K. Zeitler and S. J. Connon, Chemoselective crossed acyloin condensations: catalyst and substrate control, Synthesis, 2011, 2, 2011, 190-198

    Abstract

    The interplay between catalyst and substrate control in crossed acyloin condensation reactions has been studied. It was found that a pentafluorophenyl-substituted triazolium ion derived catalyst was capable of catalyzing highly chemoselective processes between a range of aliphatic and aromatic aldehydes utilized in a 1:1 ratio.

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    http://hdl.handle.net/2262/62630

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    Chemistry (Scholarly Publications)
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    Keywords

    Organic chemistry, aliphatic and aromatic aldehydes

    Sponsor: Irish Research Council for Science and Engineering Technology (IRCSET)

    Author's Homepage: http://people.tcd.ie/connons

    Author: CONNON, STEPHEN

    Type of material: Journal Article