• {4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate

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    2011

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    Marzec B, Mariyatra MB, McCabe T, Schmitt W, {4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate, Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1073-m1074

    Abstract

    The title compound, [CuCl2(C18H18N8)]?2CH3OH?H2O, contains a pentacoordinated Cu(II) atom bonded to the tridentate 4,6-bis[(E)-1-methyl-2-(pyridin-2-ylmethylidene)hydrazinyl]pyrimidine ligand and two Cl atoms. The geometry around the CuII atom is distorted square-pyramidal. The molecules pack in the crystal structure via O-HCl, O-HN, C-HCl and C-HO hydrogen bonds, C-H and - interactions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine interactions are 3.750 (3) and 3.850 (3) ?, respectively], forming sheet-like assemblies.

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    http://hdl.handle.net/2262/60824

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    Chemistry (Scholarly Publications)
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    Keywords

    Chemistry, Crystallography

    Sponsor: Science Foundation Ireland (SFI)
    Grant Number: 08/IN.1/I2047

    Sponsor: Science Foundation Ireland (SFI)
    Grant Number: 06/RFP/CHE174

    Author's Homepage: http://people.tcd.ie/tmccabe

    Author: MCCABE, THOMAS

    Author: SCHMITT, WOLFGANG

    Author: MARZEC, BARTOSZ

    Type of material: Journal Article