Axial Coordination Phenomena in Highly Substituted Porphyrins. Crystal Structure of the Polymeric (2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetranitroporphyrinato)zinc(II), [{Zn(oetnp)}n]
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Royal Society of Chemistry
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M. O. Senge, K. M. Smith, Axial Coordination Phenomena in Highly Substituted Porphyrins. Crystal Structure of the Polymeric (2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetranitroporphyrinato)zinc(II), [{Zn(oetnp)}n], Journal of the Chemical Society, Chemical Communications, 1994, 923 - 924
Abstract
The polymeric structure of the sterically strained and non-planar porphyrin [{ZnIIoetnp}n] is determined by X-ray crystallography; polymerization is achieved by utilization of the nitro-groups for axial ligation to the zinc(II) centre.
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Sponsor: Deutsche Forschungsgemeinschaft (DFG)
Author's Homepage: http://people.tcd.ie/sengem
Publisher: Royal Society of Chemistry
Type of material: Journal Article