Nitrile and non-nitrile pyridine products from the reaction of 2-cyano- 3-(x-nitrophenyl)prop-2-enamides with methyl 3-oxobutanoate
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1999Access:
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O'Callaghan, C.N., McMurry, T.B.H., Draper, S.M., Champeil, E., Nitrile and non-nitrile pyridine products from the reaction of 2-cyano- 3-(x-nitrophenyl)prop-2-enamides with methyl 3-oxobutanoate , Journal of Chemical Research - Part S, 12, 1999, 690, 691ADownload Item:
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Abstract:
The reaction of 2-cyano-3-(x-nitrophenyl)prop-2-enamides with methyl 3-oxobutanoate affords methyl 4-aryl-3-cyano-6-methyl-2-oxo-1,2-dihydropyridine-5-carboxylates, methyl 4-aryl-5-cyano-2-hydroxy-2-methyl-6-oxopiperidine-3-carboxylates, methyl 4-aryl-3-carbamoyl-6-methyl-2-oxo-1,2,3,4-tetrahydropyridine-5-carboxylates (the molecular structure of one of which has been confirmed by X-ray diffraction) and methyl 4-aryl-3-hydroxy-6-methyl-2-oxo-1,2-dihydropyridine-5-carboxylates.
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http://people.tcd.ie/smdraperhttp://people.tcd.ie/tmcmurry
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Author: DRAPER, SYLVIA MARY; MC MURRY, THOMAS
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Journal of Chemical Research - Part S;12;
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