(2,3,7,8,12,13,17,18-Octa-ethyl-5-phenyl-porphyrinato)platinum(II).
Citation:
Senge MO, Richter J, (2,3,7,8,12,13,17,18-Octa-ethyl-5-phenyl-porphyrinato)platinum(II)., Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1077Download Item:
Abstract:
The title compound, [Pt(C42H48N4)], was obtained through metallation of the corresponding free base with PtCl2, followed by crystallization from methylene chloride/methanol. The molecule exhibits an almost planar macrocycle with an average deviation of the 24 macrocyclic atoms from their least-squares plane (24) of 0.04 ? and an average Pt-N bond length of 2.022 ?. Despite the unsymmetrical substitution pattern, there is no significant difference between distortion of the geometry at the phenyl substituted meso position and those of unsubstituted meso positions.
Sponsor
Grant Number
Science Foundation Ireland (SFI)
09/IN.1/B2650
Author's Homepage:
http://people.tcd.ie/sengemDescription:
PUBLISHED
Author: SENGE, MATHIAS
Type of material:
Journal ArticleCollections
Series/Report no:
Acta crystallographica. Section E, Structure reports online67
Pt 8
Availability:
Full text availableKeywords:
Physical chemistry, CrystallographySubject (TCD):
Nanoscience & MaterialsDOI:
http://dx.doi.org/10.1107/S1600536811026882ISSN:
1600-5368Metadata
Show full item recordLicences: