dc.contributor.author | ROZAS, ISABEL | en |
dc.contributor.author | DIEZ CECILIA, ELENA | en |
dc.contributor.author | KELLY, BRENDAN | en |
dc.date.accessioned | 2011-11-15T15:40:16Z | |
dc.date.available | 2011-11-15T15:40:16Z | |
dc.date.issued | 2011 | en |
dc.date.submitted | 2011 | en |
dc.identifier.citation | Elena Diez-Cecilia, Brendan Kelly, Isabel Rozas, One-step double reduction of aryl nitro and carbonyl groups using hydrazine, Tetrahedron Letters, 52, 50, 2011, 6702-6704 | en |
dc.identifier.other | Y | en |
dc.identifier.uri | http://hdl.handle.net/2262/60702 | |
dc.description | PUBLISHED | en |
dc.description.abstract | Single-step reduction of aryl nitro and carbonyl groups to the corresponding synthetically useful alkyl-anilines occurs with excellent yields by treatment with hydrazine and a base in a solvent-free reaction. The method has been applied to a broad range of compounds with different properties. Investigations into the mechanism of the reduction reveal that each group is reduced independently. A mechanism is proposed for this novel reduction of aromatic nitro groups. | en |
dc.description.sponsorship | The authors are grateful to IRCSET (E.D.C.) and HEAPRTLI-5 (B.K.) for financial support, and are indebted to
Dr. John O?Brien for NMR studies. | en |
dc.format.extent | 6702-6704 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Tetrahedron Letters | en |
dc.relation.ispartofseries | 52 | en |
dc.relation.ispartofseries | 50 | en |
dc.rights | Y | en |
dc.subject | Physical chemistry | en |
dc.subject | carbonyl | en |
dc.subject | aryl nitro | en |
dc.title | One-step double reduction of aryl nitro and carbonyl groups using hydrazine | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/rozasi | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/kellyb12 | en |
dc.identifier.rssinternalid | 75311 | en |
dc.identifier.rssuri | http://dx.doi.org/10.1016/j.tetlet.2011.09.112 | en |
dc.contributor.sponsor | Irish Research Council for Science and Engineering Technology (IRCSET) | en |
dc.contributor.sponsor | Higher Education Authority (HEA) | en |