Browsing Chemistry by Subject "PCET"
Now showing items 1-2 of 2
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High-valent dinuclear bis-μ-hydroxo complexes for PCET reactivity
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2021)High valent dinuclear bis-μ-hydroxo transition metals complexes are hypothesised to play a potentially crucial role in several enzymatic mechanism involving their high-valent dinuclear bis-μ-oxo counterparts such as soluble ... -
Phenol Oxidation by a Nickel(III)-Fluoride Complex: Exploring the Influence of the Proton Accepting Ligand in PCET Oxidation
(2020)In order to gain insight into the influence of the H+‐accepting terminal ligand in high‐valent oxidant mediated proton coupled electron transfer (PCET) reactions, the reactivity of a high valent nickel–fluoride complex ...