Browsing Chemistry by Subject "Macrocycles"
Now showing items 1-3 of 3
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Incremental Introduction of Organocatalytic Activity into Conformationally Engineered Porphyrins
(2019)To study the correlation of macrocycle nonplanarity and catalytic activity of free base porphyrins in detail, a series of six tetraphenylporphyrins with graded degree of β‐ethyl substitution (“H2EtxTPPs” 1–6; x = 0, 2, 4, ... -
Nonplanar Porphyrins by N-Substitution: A Neglected Pathway
(2018)N‐substitution of porphyrins has been a neglected route towards nonplanar porphyrins for the past decades. Previously, they featured in a host of potential medicinal and biochemical applications. However, tailored syntheses ... -
Structural effects of meso-halogenation on porphyrins
(2021)The use of halogens in the crystal engineering of supramolecular porphyrin assemblies has been a topic of strong interest over the past decades. With this in mind we have characterized a series of direct meso-halogenated ...