Browsing Chemistry by Subject "Electrocatalytic water"
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Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism
(2018)Experiments mixing the stable 16e 5-coordinate complexes [RhCp∗Ar2] (Cp∗ = C5Me5; Ar = C6F5, C6F3Cl2-3,5) uncover fast aryl transmetalations. Unexpectedly, as supported computationally, these exchanges are not spontaneous, ...