Browsing Chemistry (Scholarly Publications) by Author "SCHULZKE, CAROLA"
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The difference one ligand atom makes an altered oxygen transfer reaction mechanism caused by an exchange of selenium for sulfur
SCHULZKE, CAROLA (Elsevier, 2010)The influence of sulfur versus selenium coordination to molybdenum on the oxo transfer reaction mechanisms of functional models for oxidoreductases has been studied. The solution structure of the dimeric molybdenum compound ... -
Synthesis, characterization and structural analysis of isostructural dinuclear molybdenum and tungsten oxo-bis-mu-sulfido-benzenedithiolene complexes
SCHULZKE, CAROLA (Elsevier, 2010)Reactions of the molybdenum and tungsten precursors [MO2S2]2? with equimolar amounts of benzenedithiol in acetonitrile give the title compounds [M2O2(?-S)2(bdt)2]2? with M = Mo, W and bdt = benzene-dithiolate. In case a ... -
Temperature Dependent Electrochemistry - a Versatile Tool for Investigations of Biology Related Topics
SCHULZKE, CAROLA (Royal Society of Chemistry, 2009)Temperature dependent electrochemistry can be efficiently used to determine very different properties of the investigated system, such as thermodynamic parameters of redox processes (especially the entropy), the degeneration ...