Browsing Chemistry (Theses and Dissertations) by Subject "Bioinorganic Chemistry"
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Activation of MnIIMnIII-Peroxides with Relevance to the Catalytic Cycle of Ib RNRs
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2023)The understanding of the catalytic cycle of Ib ribonucleotide reductases (RNRs) has been hindered by the inability to trap the species formed following reaction of superoxide (O2-) and the MnII2 active site. This unknown ... -
Generation and Reactivity of Late Transition Metal Hydr(oxo) Complexes Supported by Tripodal Carboxamidate Ligand
(Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2022)Metal oxo complexes (M=O) are important mediators of oxidative transformations in biological systems.1 Their high reactivity and transient nature have limited their study, with only a handful of well characterized oxo ...