Browsing Chemistry (Theses and Dissertations) by Author "MAGHERUSAN, ADRIANA MARIA"
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Mimicking ribonucleotide reductases: Biomimetic manganese complexes and their reaction with superoxide
MAGHERUSAN, ADRIANA MARIA (Trinity College Dublin. School of Chemistry. Discipline of Chemistry, 2019)An important discovery in class Ib ribonucleotide reductase’s chemistry has been the identification of a MnII2 active site, that required a superoxide anion (O2•–), rather than dioxygen (O2), to access a high-valent MnII2 ...