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dc.contributor.authorSenge, Mathias
dc.date.accessioned2021-02-25T14:44:15Z
dc.date.available2021-02-25T14:44:15Z
dc.date.issued2020
dc.date.submitted2020en
dc.identifier.citationFlanagan, Keith J., Ryan, Aoife A., Twamley, Brendan and Senge, Mathias O., "Influence of meso-linker attachment on the formation of core···π interactions in urea-functionalized porphyrins", Zeitschrift für Naturforschung B, 2020, vol. 75, no. 8, pp. 755-764en
dc.identifier.otherY
dc.identifier.urihttp://hdl.handle.net/2262/95386
dc.description.abstractThe ability to cover the face of a porphyrin macrocycle selectively is an attractive feature for concepts such as catalysis and anion binding that are reliant on porphyrin core interactions. Herein, we have synthesized a family of mono-urea functionalized porphyrin complexes with intent to investigate their potential to form coreꞏꞏꞏπ interactions selectively to one face of the porphyrin macrocycle. By altering the distance between the urea moiety and the porphyrin through direct linkage or introducing a linker group we can control the formation of the core interactions. This is clearly seen in the crystal structure of 1-phenyl-3-(2-([10,15,20- triphenylporphyrinato]zinc(II)-5-yl)phenyl)urea where a unique face capping effect is demonstrated. In the crystal of this complex, there is a hydrogen-bonding network between the urea group and the axial methanol ligand forming head-to-tail aggregates with the Zn–O axis all molecules pointing in one direction.en
dc.format.extent755-764en
dc.language.isoenen
dc.relation.ispartofseriesZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences;
dc.relation.ispartofseries75;
dc.relation.ispartofseries8;
dc.rightsYen
dc.subjectPorphyrinsen
dc.subjectUrea formationen
dc.subjectCrystal structureen
dc.subjectSuzuki reactionen
dc.subjectSonogashira reactionen
dc.titleInfluence of meso-linker attachment on the formation of core···π interactions in urea-functionalized porphyrinsen
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengem
dc.identifier.rssinternalid224212
dc.identifier.doihttp://dx.doi.org/10.1515/znb-2020-0099
dc.rights.ecaccessrightsopenAccess
dc.contributor.sponsorScience Foundation Irelanden
dc.contributor.sponsorGrantNumberIvP 13/IA/1894en


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