dc.contributor.advisor | Connon, Stephen | |
dc.contributor.author | Kavanagh, Sarah | |
dc.date.accessioned | 2019-11-06T16:32:58Z | |
dc.date.available | 2019-11-06T16:32:58Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Sarah Kavanagh, 'The development of novel organocatalysts for asymmetric methylene transfer in the Corey-Chaykovsky reaction', [thesis], Trinity College (Dublin, Ireland). School of Chemistry, 2012, pp 309 | |
dc.identifier.other | THESIS 9754 | |
dc.identifier.uri | http://hdl.handle.net/2262/90253 | |
dc.description.abstract | To date, the enantioselective preparation of terminal three-membered heterocycles via the Corey-Chaykovsky (CC) reaction has been characterised by unsatisfactory
enantioselectivities. In the benchmark literature report involving asymmetric methylene transfer to benzaldehyde, the terminal epoxide product was afforded in 57% ee, while in the benchmark literature report involving asymmetric methylene transfer to an imine, the terminal aziridine product was formed in just 19% ee. Both of these procedures require the use of (superjstoichiometric quantities (one or two equivalents respectively) of chiral sulfide. | |
dc.format | 1 volume | |
dc.language.iso | en | |
dc.publisher | Trinity College (Dublin, Ireland). School of Chemistry | |
dc.relation.isversionof | http://stella.catalogue.tcd.ie/iii/encore/record/C__Rb15157604 | |
dc.subject | Chemistry, Ph.D. | |
dc.subject | Ph.D. Trinity College Dublin. | |
dc.title | The development of novel organocatalysts for asymmetric methylene transfer in the Corey-Chaykovsky reaction | |
dc.type | thesis | |
dc.type.supercollection | thesis_dissertations | |
dc.type.supercollection | refereed_publications | |
dc.type.qualificationlevel | Doctoral | |
dc.type.qualificationname | Doctor of Philosophy (Ph.D.) | |
dc.rights.ecaccessrights | openAccess | |
dc.format.extentpagination | pp 309 | |
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