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dc.contributor.authorSCHMITT, WOLFGANGen
dc.date.accessioned2014-04-08T10:02:32Z
dc.date.available2014-04-08T10:02:32Z
dc.date.issued2010en
dc.date.submitted2010en
dc.identifier.citationSchmitt W, Zhang L, Anson CE, Powell AK, Aggregation of dinuclear {Fe2hpdta} units to form polynuclear oxy/hydroxy-bridged Fe(III) coordination complexes., Dalton transactions (Cambridge, England : 2003), 39, 42, 2010, 10279-85en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/68429
dc.descriptionPUBLISHEDen
dc.description.abstractAn approach for the preparation of oxy/hydroxy briged FeIII clusters that takes advantage of hydrolytic condensations of well defined {Fe2hpdta(H2O)4} building units is presented. Co-ligands such as tripodal H3tea or bidentate organic bases such as ethylenediamine (enH2) can be used to complete the coordination spheres of the FeIII centres and stabilise unsymmetrical iron-oxo clusters with non-zero magnetic ground spin-states. This strategy led to the isolation of a pentanuclear complex [Fe5(?3-O)(hpdta)(H2tea)(Htea)2)(tea)]?{N(C2H4OH)3}?2EtOH?7H2O (1) and a nonanuclear coordination complex [Fe9(?3-O)5(?-OH)5(en)6(hpdta)2](NO3)2?7H2O (2).en
dc.format.extent10279-85en
dc.language.isoenen
dc.relation.ispartofseriesDalton transactions (Cambridge, England : 2003)en
dc.relation.ispartofseries39en
dc.relation.ispartofseries42en
dc.rightsYen
dc.subjectChemistryen
dc.titleAggregation of dinuclear {Fe2hpdta} units to form polynuclear oxy/hydroxy-bridged Fe(III) coordination complexes.en
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorIrish Research Council for Science and Engineering Technology (IRCSET)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/schmittwen
dc.identifier.rssinternalid69923en
dc.identifier.doihttp://dx.doi.org/10.1039/c0dt00655fen
dc.rights.ecaccessrightsOpenAccess
dc.contributor.sponsorGrantNumber08/RFP/CHE1273en
dc.contributor.sponsorGrantNumber08/IN.1/I2047en
dc.subject.TCDThemeNanoscience & Materialsen


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