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dc.contributor.authorSENGE, MATHIASen
dc.date.issued2010en
dc.date.submitted2010en
dc.identifier.citationDavis, M.; Senge, M. O.; Locos, O. B., Anthracenylporphyrins, Zeitschrift fuer Naturforschung, 65b, 2010, 1472 - 1484en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/67505
dc.descriptionPUBLISHEDen
dc.description.abstractWe report the synthesis and characterization of meso-anthracenylporphyrins with zinc and nickel metal centers. A variety of novel aryl and alky meso substituted anthracenylporphyrins were synthesized via step-wise Suzuki cross-coupling reactions using anthracenyl boronates. This method was compared to standard syntheses based on condensation reactions to yield anthracenylporphyrins of the A2B2- and A3B-type. This was complemented by the synthesis of a number of the functionalized anthracene derivatives via Suzuki couplings for use in porphyrin functionalization. Selected systems were subjected to single-crystal X-ray analysis which revealed an unusual close packing for nickel(II) anthracenylporphyrins.en
dc.description.sponsorshipThis work was supported by a grant from Science Foundation Ireland (SFI P.I. 09/IN.1/B2650). We are indebted to Dr. T. McCabe for some of the X-ray data collections.en
dc.format.extent1472en
dc.format.extent1484en
dc.language.isoenen
dc.relation.ispartofseriesZeitschrift fuer Naturforschungen
dc.relation.ispartofseries65ben
dc.rightsYen
dc.subject.otherporphyrins
dc.titleAnthracenylporphyrinsen
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengemen
dc.identifier.rssinternalid71030en
dc.rights.ecaccessrightsOpenAccess
dc.contributor.sponsorGrantNumber09/IN.1/B2650en


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