Browsing Chemistry (Scholarly Publications) by Title
Now showing items 30-49 of 557
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The balance between closed and open forms of spiropyrans in the solid state
(2010)We present three new crystal structures of members from the photochromic spiropyran family, including a rare example of an open (merocyanine) form. The molecular structures are systematically compared with existing ... -
Band gap anomalies of the (ZnM2O4)-O-III (M-III = Co, Rh, Ir) spinels
(2011)Development of high figure-of-merit p-type transparent conducting oxides has become a global research goal. ZnM 2 IIIO 4 (M III = Co, Rh, Ir) spinels have been identified as potential p-type materials, with ZnIr 2O 4 ... -
Band gap engineering of In2O3 by alloying with Tl2O3
(2013)Efficient modulation of the bandgap of In 2 O 3 will open up a route to improved electronic properties. We demonstrate using ab initio calculations that Tl incorporation into In 2 O 3 reduces the band gap and ... -
Benzyl 4-ethyl-3-methyl-5-(phthalimidomethyl)pyrrole-2-carboxylate
(2007)The title compound, C24H22N2O4, forms weak inter- and intramolecular N?H O hydrogen bonds. Additional intermolecular C?H O interactions give rise to a threedimensional network in the crystal structure. -
Benzylic Oligothioethers as Ditopic Ligands for Group 6 Transition Metal Carbonyls
(2000)The co-ordination preferences of a family of novel thioethers based on (alkylsulfanylmethyl)benzene were examined. The alkyl chain length and the number and position of the thioether substituents were varied. The ligands ... -
Bidentate N-Heterocyclic carbene complexes of group 13 trihydrides and trihalides.
(2002)top Treatment of the potentially chelating bis-carbene, 1,2-ethylene-3,3′-di-tert-butyl-diimidazole-2,2′-diylidene, EtIBut, with [MH3(NMe3)], M = Al, Ga, In, in a 1 ∶ 1 or 1 ∶ 2 stoichiometery led to good yields of the ... -
Bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N",N'")-iron(III) Perchlorate Bis(methanol) Solvate, [Fe(III)oep(HOCH3)2][ClO4].2CH3OH
(International Union of Crystallography, 1996)Simple treatment of [FeIII(oep)Cl] (where oep is octaethylporphyrin) with dilute perchloric acid leads to facile preparation of the title compound, [Fe(C36H44N4)(CH4O)2](ClO4).2CH4O. The structure consists of discrete ... -
Bis[anhydro-meso-rhodochlorinato XV methyl ester)zinc(II)]
(International Union of Crystallography, 1997)The title compound bis[(methyl 8,13-diethyl-2,21,22,23-tetrahydro- 3,7,12,17-tetramethyl-23-oxo-3H-benzo[at]porphyrin-18-carboxylato-Kappa4N)- zinc(II)], [Zn(C33H34N4O3)]2, has similar structural characteristics to the ... -
Boride cluster fusion via an M4-unit (M=Cu, Ag): molecular structure of [PPN][{Ru4H(CO)12B}2Cu4(m-Cl)][Cl]
(1992)The reaction of [ppn][Ru4H(CO)12BH] with [Cu(MeCN)4][BF4] in the presence of [ppn][Cl] yields [ppn][{Ru4H(CO)12B}2-Cu4(?-Cl)][Cl], which has been structurally characterised; the introduction of silver in place of copper ... -
Bridging the Gap between Porphyrins and Porphycenes: Substituent-Position-Sensitive Tautomerism and Photophysics in meso-Diphenyloctaethylporphyrins
(2011)henylporphyrin (1) is characterized by an inner cavity with a rectangular shape and small NH???N distances. It resembles porphycene, a constitutional isomer of porphyrin known for its strong intramolecular hydrogen ... -
The btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] binding motif: A new versatile terdentate ligand for supramolecular and coordination chemistry
(2014)Ligands containing the btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] motif have appeared with increasing regularity over the last decade. This class of ligands, formed in a one pot ‘click’ reaction, has been studied for various ... -
Carbazole-linked porphyrin dimers for organic light emitting diodes: Synthesis and initial photophysical studies
(2011)Carbazole linked porphyrin dimers were synthesized in good yields via stepwise Suzuki coupling reactions using bromoporphyrins and borylated carbazoles as the precursors, the latter of which were synthesized via known ... -
Carbon nanotube based modified electrode biosensors. Part 1. Electrochemical studies of the flavin group redox kinetics at SWCNT/glucose oxidase composite modified electrodes.
(Electrochemical Science Group, 2008)The redox behaviour of glucose oxidase adsorbed on glassy carbon electrodes which have been modified with a dispersed mesh of single wall carbon nanotubes is probed both qualitatively and quantitatively using cyclic ... -
Catalytic (asymmetric) methylene transfer to aldehydes
(2010)An investigation into the poor activity of sulfides as catalysts for sulfonium-ylide-mediated methylene transfer to aldehydes has indicated that ylide formation is the problematic catalytic cycle step. Alkylation with ... -
Catalytic, enantio- and diastereoselective synthesis of gamma-butyrolactones incorporating quaternary stereocentres
(2012)A new, highly enantio- and diastereoselective catalytic asymmetric formal cycloaddition of aryl succinic anhydrides and aldehydes which generates paraconic acid (y-butyrolactone) derivatives is reported. -
Cation-π interactions: complexes of Guanidinium and simple aromatic systems
(2011)We have theoretically studied, in gas phase and using PCM-water solvation, the complexes established by the biologically relevant guanidinium cation and simple aromatic systems (benzene, naphthalene and pyridine). In gas ... -
Cell Proliferation Tracking Using Graphene Sensor Arrays
(2012)The development of a novel label-free graphene sensor array is presented. Detection is based on modification of graphene FET devices and specifically monitoring the change in composition of the nutritive components in ... -
CeO2 catalysed conversion of CO, NO2 and NO from first principles energetics
(2006)First principles calculations using density functional theory with corrections for on-site Coulomb interactions (DFT + U) are presented in which we compute the energy for the conversion of CO to CO2, NO2 to NO and NO to ...
