Browsing by Subject "Ribonucleotide reductases"
Now showing items 1-2 of 2
-
Mimicking class I b Mn2-ribonucleotide reductase: A MnII2 complex and its reaction with superoxide
(2018)A fascinating discovery in the chemistry of ribonucleotide reductases (RNRs) has been the identification of a dimanganese (Mn2 ) active site in class I b RNRs that requires superoxide anion (O2.- ), rather than dioxygen ... -
A MnIIMnIII-Peroxide Complex Capable of Aldehyde Deformylation
(2019)Ribonucleotide reductases (RNRs) are essential enzymes required for DNA synthesis. In class Ib Mn2 RNRs superoxide (O2.−) was postulated to react with the MnII2 core to yield a MnIIMnIII‐peroxide moiety. The reactivity of ...