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Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/60823

Title: (2,3,7,8,12,13,17,18-Octa-ethyl-5-phenyl-porphyrinato)platinum(II).
Author: SENGE, MATHIAS
Sponsor: 
Name Grant Number
09/IN.1/B2650

Author's Homepage: http://people.tcd.ie/sengem
Keywords: Physical chemistry
Crystallography
Issue Date: 2011
Publisher: International Union of Crystallography
Citation: Senge MO, Richter J, (2,3,7,8,12,13,17,18-Octa-ethyl-5-phenyl-porphyrinato)platinum(II)., Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1077
Series/Report no.: Acta crystallographica. Section E, Structure reports online;
67;
Pt 8;
Abstract: The title compound, [Pt(C42H48N4)], was obtained through metallation of the corresponding free base with PtCl2, followed by crystallization from methylene chloride/methanol. The molecule exhibits an almost planar macrocycle with an average deviation of the 24 macrocyclic atoms from their least-squares plane (24) of 0.04 Å and an average Pt-N bond length of 2.022 Å. Despite the unsymmetrical substitution pattern, there is no significant difference between distortion of the geometry at the phenyl substituted meso position and those of unsubstituted meso positions.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/60823
Related links: http://dx.doi.org/10.1107/S1600536811026882
Appears in Collections:Chemistry (Scholarly Publications)

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