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Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/59716

Title: Carbazole linked porphyrin dimers for organic light emitting diodes: Synthesis and initial photophysical studies
Author: SENGE, MATHIAS
BLAU, WERNER
RYAN, AOIFE
Sponsor: 
Name Grant Number
09/IN.1/B2650

Author's Homepage: http://people.tcd.ie/sengem
http://people.tcd.ie/wblau
http://people.tcd.ie/ryana41
Keywords: Biochemistry
porphyrins
carbazoles
Issue Date: 2011
Citation: Aoife Ryan, Brian Tuffy, Sabine Horn, Werner J. Blau, Mathias O. Senge, Carbazole linked porphyrin dimers for organic light emitting diodes: Synthesis and initial photophysical studies, Tetrahedron, 57, 43, 2011, 8248-8254
Series/Report no.: Tetrahedron
57
43
Abstract: Carbazole linked porphyrin dimers were synthesized in good yields via stepwise Suzuki coupling reactions using bromoporphyrins and borylated carbazoles as the precursors, the latter of which were synthesized via known procedures from biphenyl derivatives. For comparative purposes porphyrin-carbazole monomers were synthesized. Single layer organic light emitting diodes (OLEDs) were created to demonstrate the optical properties of these materials. Light emission from these carbazole substituted porphyrins showed better results compared to previously examined bromo substituted porphyrins with better electroluminescence and lower turn-on voltages. Dimers exhibited turn-on voltages of 3V compared to 6V for monomeric porphyrin-carbazoles.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/59716
Related links: http://dx.doi.org/10.1016/j.tet.2011.08.096
Appears in Collections:Chemistry (Scholarly Publications)

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