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Title: (5,15-Dianthracen-9-yl-10,20-dihexyl-porphyrinato)nickel(II): A planar nickel(II) porphyrin
Sponsor: Science Foundation Ireland
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Keywords: Physical chemistry
planar nickel(II) porphyrin
Issue Date: 2010
Publisher: International Union of Crystallography
Citation: Senge, M.O., Davis, M, (5,15-Dianthracen-9-yl-10,20-dihexyl-porphyrinato)nickel(II): A planar nickel(II) porphyrin, Acta Crystallographica Section E: Structure Reports Online, 66, 7, 2010, m790
Series/Report no.: Acta Crystallographica Section E: Structure Reports Online;
Abstract: The title compound, [Ni(C60H52N4)], is an example of a meso tetrasubstituted nickel(II) porphyrin with both meso aryl and alkyl residues. The molecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane ([Delta]24) of 0.01 Å and an average Ni-N bond length of 1.960 (2) Å. The NiII atom lies on a center of inversion. The structure presents a rare example for a planar nickel(II) porphyrin, as meso-substituted nickel(II) porphyrins with either only meso-aryl or with meso-alkyl residues typically exhibit a ruffled conformation.
Description: PUBLISHED
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Appears in Collections:Chemistry (Scholarly Publications)

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