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Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/40311

Title: Magnetism of wurtzite CoO nanoclusters
Author: ARCHER, THOMAS DAVID
SANVITO, STEFANO
Sponsor: Science Foundation Ireland
Author's Homepage: http://people.tcd.ie/sanvitos
http://people.tcd.ie/archert
Keywords: Atomic, molecular and chemical physics
ferromagnetism
Issue Date: 2010
Publisher: American Physical Society
Citation: Ruairi Hanafin, Thomas Archer and Stefano Sanvito, Magnetism of wurtzite CoO nanoclusters, Physical Review B, 81, 5, 2010, 054441
Series/Report no.: Physical Review B;
81;
5;
Abstract: The possibility that the apparent room-temperature ferromagnetism, often measured in Co-doped ZnO, is due to uncompensated spins at the surface of wurtzite CoO nanoclusters is investigated by means of a combination of density-functional theory and Monte Carlo simulations. We find that the critical temperature extracted from the specific heat systematically drops as the cluster size is reduced, regardless of the particular cluster shape. Furthermore the presence of defects, in the form of missing magnetic sites, further reduces TC. This suggests that even a spinodal decomposed phase is unlikely to sustain room-temperature ferromagnetism in ZnO:Co.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/40311
Related links: http://link.aps.org/doi/10.1103/PhysRevB.81.054441
Appears in Collections:Physics (Scholarly Publications)

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