E. D. Sturrock, J. D. Bull, R. E. Kirsch, R. K. Pandey, M. O. Senge, K. M. Smith, A Novel 2,18-Bridged Biliverdin Derivative, Journal of the Chemical Society, Chemical Communications, 1993, 872 - 874
Journal of the Chemical Society, Chemical Communications;
Base-catalysed dehydrohalogenation of a 3,18-bis(2-chloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which
the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal
X-ray and 1H nuclear Overhauser effect studies.
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