M. O. Senge, T. Ema, K. M. Smith, Crystal Structure of a Remarkably Ruffled Nonplanar Porphyrin - (Pyridine)(5,10,15,20-Tetra(tert-butyl)porphyrinato)zinc(II), Journal of the Chemical Society, Chemical Communications, 1995, 733 - 734
Journal of the Chemical Society, Chemical Communications;
The title compound presents the first example of a sterically ruffled porphyrin bearing only meso substituents; the degree of ruffling is severe, with Cm-displacements of up to 1 Å.
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