The University of Dublin | Trinity College -- Ollscoil Átha Cliath | Coláiste na Tríonóide
Trinity's Access to Research Archive
Home :: Log In :: Submit :: Alerts ::

TARA >
School of Chemistry >
Chemistry >
Chemistry (Scholarly Publications) >

Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/40135

Title: Bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N",N'")-iron(III) Perchlorate Bis(methanol) Solvate, [Fe(III)oep(HOCH3)2][ClO4].2CH3OH
Author: SENGE, MATHIAS
Sponsor: Deutsche Forschungsgemeinschaft (DFG)
Author's Homepage: http://people.tcd.ie/sengem
Keywords: Chemistry
[Fe(C36H44N4)(CH4O)2](ClO4).2CH4O
Issue Date: 1996
Publisher: International Union of Crystallography
Citation: M. O. Senge, Bis(methanol-O)(2,3,7,8,12,13,17,18-octaethylporphyrinato-N,N',N",N'")-iron(III) Perchlorate Bis(methanol) Solvate, [Fe(III)oep(HOCH3)2][ClO4].2CH3OH, Acta Crystallographica C, 52, 2, 1996, 302 - 305
Series/Report no.: Acta Crystallographica C;
52;
2;
Abstract: Simple treatment of [FeIII(oep)Cl] (where oep is octaethylporphyrin) with dilute perchloric acid leads to facile preparation of the title compound, [Fe(C36H44N4)(CH4O)2](ClO4).2CH4O. The structure consists of discrete [Fe(oep)(HOCH3)2]+ cations, perchlorate anions and methanol molecules of solvation, which are connected by hydrogen bonds in an infinite network. The Fe atom is located in the plane of the N atoms and is coordinated by two methanol O atoms in the axial position, with an average Fe-N distance of 2.026 (3) Å and Fe-O bond lengths of 2.159 (3) Å.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/40135
Related links: http://dx.doi.org/10.1107/S0108270195006068
Appears in Collections:Chemistry (Scholarly Publications)

Files in This Item:

File Description SizeFormat
Bis(methanol-O).pdfPublished (publisher's copy) - Peer Reviewed460.95 kBAdobe PDFView/Open


This item is protected by original copyright


Please note: There is a known bug in some browsers that causes an error when a user tries to view large pdf file within the browser window. If you receive the message "The file is damaged and could not be repaired", please try one of the solutions linked below based on the browser you are using.

Items in TARA are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback