The University of Dublin | Trinity College -- Ollscoil Átha Cliath | Coláiste na Tríonóide
Trinity's Access to Research Archive
Home :: Log In :: Submit :: Alerts ::

TARA >
School of Chemistry >
Chemistry >
Chemistry (Scholarly Publications) >

Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/40130

Title: Synthesis of porphyryl boronates with (un)saturated side chains
Author: SENGE, MATHIAS
SERGEEVA, NATALIA
Sponsor: Science Foundation Ireland
Author's Homepage: http://people.tcd.ie/sengem
http://people.tcd.ie/sergeevn
Keywords: Chemistry
boron
Issue Date: 2008
Citation: N. N. Sergeeva, V. Pablo Lopez, M. O. Senge, Synthesis of porphyryl boronates with (un)saturated side chains, Journal of Organometallic Chemistry, 693, 15, 2008, 2637 - 2640
Series/Report no.: Journal of Organometallic Chemistry
693
15
Abstract: Porphyrins with (un)saturated side–chains containing boron residues were developed as synthons for porphyrin functionalization. Porphyrins with mono and bis-substituted unsaturated boronyl residues were prepared in good yields (52–66 %) using a cross–metathesis approach in the presence of Grubbs I-generation catalysts. In all cases complete E–stereoselectivity (100 %) was observed. Furthermore, formal cross–metathesis products with α,β–unsaturated chains smoothly underwent addition with bis(pinacolato)diboron [(Me4C2O2)B–B(O2C2Me4)] to yield the corresponding saturated boron compounds in 6070 % yields.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/40130
Related links: http://dx.doi.org/10.1016/j.jorganchem.2008.05.006
Appears in Collections:Chemistry (Scholarly Publications)

Files in This Item:

File Description SizeFormat
Synthesis of porphyryl.pdfPublished (author's copy) - Peer Reviewed112.45 kBAdobe PDFView/Open


This item is protected by original copyright


Please note: There is a known bug in some browsers that causes an error when a user tries to view large pdf file within the browser window. If you receive the message "The file is damaged and could not be repaired", please try one of the solutions linked below based on the browser you are using.

Items in TARA are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback