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Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/38806

Title: Sonication of porphyrin-nanotube composites: a cautionary tale
Author: GIORDANI, SILVIA
BLAU, WERNER
Sponsor: Science Foundation Ireland
Author's Homepage: http://people.tcd.ie/giordans
http://people.tcd.ie/wblau
Keywords: Chemistry
Issue Date: 2007
Publisher: Wiley
Citation: Mhuircheartaigh E. N., Blau W. J., Prato M. and Giordani S, Sonication of porphyrin-nanotube composites: a cautionary tale, Physica Status Solidi (b), 244, 11, 2007, 4227 4230
Series/Report no.: Physica Status Solidi (b);
244;
11;
Abstract: We report the spectroscopic changes of tetraphenylporphyrin carbon nanotube composites in a variety of chlorinated solvents such as chloroform, dichloroethane and dichlorobenzene as a result of sonication. Detailed data analysis suggests that protonation of the porphyrin core nitrogen atoms occurs as a result of sonodegradation of the solvent molecules. Extreme care must be taken when working with carbon nanotube composite solutions in chlorinated solvents, as sonication is always employed to disperse the nanotubes. This finding is of enormous relevance to the materials chemistry community since these solvents are widely used in preparation of carbon nanotube composite solutions. When working with molecules that are capable of acting as a base some amount of protonation is inevitable and this may dramatically change the physicochemical properties of the composite materials.
Description: PUBLISHED
URI: http://hdl.handle.net/2262/38806
Related links: http://dx.doi.org/10.1002/pssb.200776160
Appears in Collections:Chemistry (Scholarly Publications)

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