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Please use this identifier to cite or link to this item: http://hdl.handle.net/2262/31326

Title: Exploration of the reaction of potassium organotrifluoroborates with porphyrins
Author: SENGE, MATHIAS
Sponsor: Science Foundation Ireland
Author's Homepage: http://people.tcd.ie/sengem
Keywords: Chemistry
Issue Date: 2009
Citation: Sabine Horn, Bob Cundell and Mathias O. Senge, Exploration of the reaction of potassium organotrifluoroborates with porphyrins, Tetrahedron Letters, 50, 21, 2009, 2562 - 2565
Series/Report no.: Tetrahedron Letters
50
21
Abstract: A general method that uses potassium organotrifluoroborates in the Suzuki–Miyaura cross-coupling reaction with ring-brominated porphyrins has been investigated. The reaction conditions tolerate various functional groups and are applicable to the meso- and β-position as well as to aryl- and alkyl-substituted porphyrins. Depending on the nature of the potassium organotrifluoroborate, the coupling products can be obtained in yields of up to 75%.
Description: PUBLISHED
URI: http://dx.doi.org/10.1016/j.tetlet.2009.03.098
http://hdl.handle.net/2262/31326
Appears in Collections:Chemistry (Scholarly Publications)

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