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dc.contributor.authorGarcia Melchor, Maxen
dc.contributor.authorSchmitt, Wolfgangen
dc.date.accessioned2020-10-05T12:39:03Z
dc.date.available2020-10-05T12:39:03Z
dc.date.issued2020en
dc.date.submitted2020en
dc.identifier.citationAko, A. M.; Kathalikkattil, A. C.; Elliott, R.; Soriano-López, J.; McKeogh, I. M.; Zubair, M.; Twamley, B.; Zhu, N.; García-Melchor, M.; Kruger, P. E.; Schmitt, W., Synthetic approaches to metallo-supramolecular Co(II) polygons and potential use for H2O oxidation, Inorganic Chemistry, 59, 2020, 14432-en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/93681
dc.descriptionPUBLISHEDen
dc.description.abstractMetal-directed self-assembly has been applied to prepare supramolecular coordination polygons which adopt tetrahedral (1) or trigonal disklike topologies (2). In the solid state, 2 assembles into a stable halide–metal–organic material (Hal-MOM-2), which catalyzes H2O oxidation under photo- and electrocatalytic conditions, operating with a maximum TON = 78 and TOF = 1.26 s–1. DFT calculations attribute the activity to a CoIII-oxyl species. This study provides the first account of how CoII imine based supramolecules can be employed as H2O oxidation catalysts.en
dc.format.extent14432en
dc.language.isoenen
dc.relation.ispartofseriesInorganic Chemistryen
dc.relation.ispartofseries59en
dc.rightsYen
dc.titleSynthetic approaches to metallo-supramolecular Co(II) polygons and potential use for H2O oxidationen
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/garciammen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/schmittwen
dc.identifier.rssinternalid220681en
dc.identifier.doihttps://doi.org/10.1021/acs.inorgchem.0c02182en
dc.rights.ecaccessrightsopenAccess
dc.contributor.sponsorGrantNumberCoG 2014− 647719en
dc.contributor.sponsorGrantNumber13/IA/1896en
dc.identifier.orcid_id0000-0003-1348-4692en


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