Structural investigation of 5,10-A2B2-type porphyrins Palladium(II) and zinc(II) complexes of 5,10-dibromo-15,20-bis(4-methylphenyl)porphyrin.
Citation:
Senge, M. O.; Zawadzka, M., Structural investigation of 5,10-A2B2-type porphyrins Palladium(II) and zinc(II) complexes of 5,10-dibromo-15,20-bis(4-methylphenyl)porphyrin., Acta Crystallographica, C70, 2014, 1143 1146Download Item:

Abstract:
The analysis of [5,10-dibromo-15,20-bis(4-methylphenyl)por-
phyrinato]palladium(II), [Pd(C
34
H
22
Br
2
N
4
)], and [5,10-di-
bromo-15,20-bis(4-methylphenyl)porphyrinato](methanol)-
zinc(II), [Zn(C
34
H
22
Br
2
N
4
)(CH
4
O)], reveals a small but
localized influence of the bromine residues on the conforma-
tion of the macrocycle. A comparison of the 5,10-dibromo
substituent pattern with literature data for 5,15-dibromo-
porphyrins shows similar in-plane distortions in both but a
different mix of out-of-plane distortion modes for the
different regiochemical arrangements.
Sponsor
Grant Number
Science Foundation Ireland (SFI)
SFI P.I. 09/IN.1/B2650
Author's Homepage:
http://people.tcd.ie/sengemDescription:
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Author: SENGE, MATHIAS
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Journal ArticleCollections:
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Acta CrystallographicaC70
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http://dx.doi.org/10.1107/S2053229614023687Licences: