dc.contributor.author | GUNNLAUGSSON, THORFINNUR | en |
dc.date.accessioned | 2015-01-26T16:51:29Z | |
dc.date.available | 2015-01-26T16:51:29Z | |
dc.date.issued | 2014 | en |
dc.date.submitted | 2014 | en |
dc.identifier.citation | Kitchen,Jonathan A. J.A., Martinho,Paulo Nuno P.N., Morgan,Grace G. G.G., Gunnlaugsson,Thorfinnur T., Synthesis, crystal structure and EPR spectroscopic analysis of novel copper complexes formed from N-pyridyl-4-nitro-1,8-naphthalimide ligands, Dalton Transactions, 43, 17, 2014, 6468-6479 | en |
dc.identifier.issn | 14779226 | en |
dc.identifier.other | Y | en |
dc.identifier.uri | http://hdl.handle.net/2262/73129 | |
dc.description | PUBLISHED | en |
dc.description.abstract | The mono-dentate, pyridyl containing, nitro naphthalimide ligands N-(4-pyridyl)-4-nitro-1,8-naphthalimide (L1) and N-(3-pyridyl)-4-nitro-1,8-naphthalimide (L2) were prepared and complexed with a selection of copper salts [Cu(OAc)2, Cu(CF3SO3)2 and Cu(ClO4)2]. Crystallographic studies were undertaken and revealed that dinuclear acetate bridged complexes resulted from reactions with Cu(OAc)2, while mononuclear systems resulted from reactions with Cu(CF3SO3)2 and Cu(ClO4)2. Despite the differing coordination environments the naphthalimide based ligands provided a range of interesting π-based interactions in the form of ππ, anionπ, nitroπ, solventπ and C[double bond, length as m-dash]Oπ associations. Solid state EPR spectra were in agreement with the coordination environments observed from crystallography. | en |
dc.description.sponsorship | We would like to thank, TCD, UCD, IRCSET (JAK Postdoctoral
Fellowship) and SFI PI 2010 grant (TG) for financial support to
this project | en |
dc.format.extent | 6468-6479 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Dalton Transactions | en |
dc.relation.ispartofseries | 43 | en |
dc.relation.ispartofseries | 17 | en |
dc.rights | Y | en |
dc.subject | mono-dentate, pyridyl containing, nitro naphthalimide ligands | en |
dc.subject.lcsh | mono-dentate, pyridyl containing, nitro naphthalimide ligands | en |
dc.title | Synthesis, crystal structure and EPR spectroscopic analysis of novel copper complexes formed from N-pyridyl-4-nitro-1,8-naphthalimide ligands | en |
dc.type | Journal Article | en |
dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/gunnlaut | en |
dc.identifier.rssinternalid | 99330 | en |
dc.identifier.doi | http://dx.doi.org/10.1039/c3dt53323a | en |
dc.rights.ecaccessrights | openAccess | |