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dc.contributor.authorGUNNLAUGSSON, THORFINNURen
dc.date.accessioned2015-01-26T16:50:50Z
dc.date.available2015-01-26T16:50:50Z
dc.date.issued2014en
dc.date.submitted2014en
dc.identifier.citationByrne,Joseph P. J.P., Kitchen,Jonathan A. J.A., Gunnlaugsson,Thorfinnur T., The btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] binding motif: A new versatile terdentate ligand for supramolecular and coordination chemistry, Chemical Society Reviews, 43, 15, 2014, 5302-5325en
dc.identifier.issn03060012en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/73127
dc.descriptionPUBLISHEDen
dc.description.abstractLigands containing the btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] motif have appeared with increasing regularity over the last decade. This class of ligands, formed in a one pot ‘click’ reaction, has been studied for various purposes, such as for generating d and f metal coordination complexes and supramolecular self-assemblies, and in the formation of dendritic and polymeric networks, etc. This review article introduces btp as a novel and highly versatile terdentate building block with huge potential in inorganic supramolecular chemistry. We will focus on the coordination chemistry of btp ligands with a wide range of metals, and how it compares with other classical pyridyl and polypyridyl based ligands, and then present a selection of applications including use in catalysis, enzyme inhibition, photochemistry, molecular logic and materials, e.g. polymers, dendrimers and gels. The photovoltaic potential of triazolium derivatives of btp and its interactions with anions will also be discussed.en
dc.description.sponsorshipThe authors would like to acknowledge the Irish Research Council (IRC) Embark Initiative, IRCSET for postgraduatestudentships (to JPB) and a postdoctoral fellowship (to JAK), Science Foundation Ireland (SFI) for 2010 PI Award, and TCD School of Chemistry for financial support. We would like to thank and dedicate this review to the many people and key players listed above; their work has wonderfully influenced our research in the past few years and will, without a doubt, continue to do so in the futureen
dc.format.extent5302-5325en
dc.language.isoenen
dc.relation.ispartofseriesChemical Society Reviewsen
dc.relation.ispartofseries43en
dc.relation.ispartofseries15en
dc.rightsYen
dc.subjectLigands containing the btp [2,6-bis(1,2,3-triazol-4-yl)pyridine]en
dc.subject.lcshLigands containing the btp [2,6-bis(1,2,3-triazol-4-yl)pyridine]en
dc.titleThe btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] binding motif: A new versatile terdentate ligand for supramolecular and coordination chemistryen
dc.typeJournal Articleen
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/gunnlauten
dc.identifier.rssinternalid99327en
dc.identifier.doihttp://dx.doi.org/10.1039/c4cs00120fen
dc.rights.ecaccessrightsopenAccess
dc.contributor.sponsorGrantNumberPI 2010 awarden


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