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dc.contributor.authorBAKER, ROBERTen
dc.date.accessioned2014-06-03T13:03:53Z
dc.date.available2014-06-03T13:03:53Z
dc.date.issued2003en
dc.date.submitted2003en
dc.identifier.citationR.J. Baker, P.G. Edwards, R.D. Farley, D.M. Murphy, J.A. Platts and K.E. Voss, Low valent carbonylvanadium complexes of the triphosphorus macrocycle 12[ane]P3Et3., J. Chem. Soc., Dalton. Trans., 2003, 944, 948en
dc.identifier.otherYen
dc.identifier.urihttp://hdl.handle.net/2262/69574
dc.descriptionPUBLISHEDen
dc.description.abstractThe triphosphorus macrocycle 1,5,9-triethyl-1,5,9-triphosphacyclododecane, 12[ane]P3Et3, reacts with [V(CO)6]− under photolytic conditions to produce fac-[(12[ane]P3Et3)V(CO)3]− (1) which has been isolated as its Et4N salt. This can be oxidised to the neutral 17 electron complex fac-(12[ane]P3Et3)V(CO)3 (2), which has been characterised by EPR spectroscopy. Density functional calculations support the spectroscopic observations and give insight into the bonding. The V(0) compound cannot be further oxidised, but the macrocycle reacts with CpV(CO)4 thermally or photolytically to produce cis-[(η2-12[ane]P3Et3)V(η5-Cp)(CO)2] (3). The diamagnetic compounds have been characterised by IR and multinuclear (1H, 13C, 31P and 51V) NMR spectroscopy.en
dc.format.extent944en
dc.format.extent948en
dc.language.isoenen
dc.relation.ispartofseriesJ. Chem. Soc., Dalton. Trans.en
dc.rightsYen
dc.subjectChemistryen
dc.titleLow valent carbonylvanadium complexes of the triphosphorus macrocycle 12[ane]P3Et3.en
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/bakerrjen
dc.identifier.rssinternalid57398en
dc.identifier.doihttp://dx.doi.org/10.1039/b211105pen
dc.rights.ecaccessrightsopenAccess


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