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dc.contributor.authorSENGE, MATHIAS
dc.date.accessioned2013-10-22T10:13:03Z
dc.date.available2013-10-22T10:13:03Z
dc.date.issued2011
dc.date.submitted2011en
dc.identifier.citationPlunkett, S.; Senge, M. O., Synthesis of Unsymmetrically meso-Substituted Porphyrins, ECS Transactions, 35, 2011, 147-157en
dc.identifier.otherY
dc.identifier.urihttp://hdl.handle.net/2262/67528
dc.descriptionPUBLISHEDen
dc.description.abstractThe continued development of new medicinal and industrial uses of highly substituted porphyrins, especially in the fields of photodynamic therapy, nonlinear optics and electron transfer systems, has led to a resurgent interest in developing new methodologies for porphyrin synthesis. The porphyrins in question, so called ABCD-type porphyrins, have mixed meso substituents, making them highly unsymmetric and thus not synthetically available through classical condensation routes. Synthetic strategies towards the formation of meso substituted porphyrins have been extensively researched over the last decade with various routes now available. While methods using mixed condensations are still preferred for systems with high symmetry, the number of possible products makes it an unviable route for the synthesis of the more useful non symmetric porphyrins. To this end novel syntheses of ABCD-type porphyrins have been developed using synthetic manipulations of pre-formed porphyrin scaffolds with various organolithium reagents and Pd catalysed metal couplingsen
dc.description.sponsorshipOur recent work in this area was supported by a grant from Science Foundation Ireland (SFI P.I. 09/IN.1/B2650).en
dc.format.extent147-157en
dc.language.isoenen
dc.relation.ispartofseriesECS Transactions;
dc.relation.ispartofseries35;
dc.rightsYen
dc.subject.otherPorphyrins
dc.titleSynthesis of Unsymmetrically meso-Substituted Porphyrinsen
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/sengem
dc.identifier.rssinternalid78005
dc.rights.ecaccessrightsOpenAccess


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